An animê like Acchi Kocchi and Toradora? (with a tsundere main character)

Oreimo is the closest to such a animê since Kirino may or may not be one of the mais famous tsundere around. (Keep in mind that even if a boy there is the main character its mais focused around her.)

Hentai ouji to waranai neko ( In english "The hentai prince and the stray cat" ) also features a tsundere character named Azuki Azusa, altough she doesnt get as much attention as Kirino get (Also a guy here is the main protag. )

Well, The Familiar of Zero has Miss Louise Françoise Le blanc de La Vallière who is debatable one of anime's most (in?)famous tsunderes.