Well my first pic was Alice from "Pandora Hearts"; for my "Second" fave I will pic the female character who's character I liked most on a professional level.
Suou Pavlichenko from "Darker than Black: Gemini of the Meteor"
Magnificent character design, development, ect. She really explored what it meant to be a contractor, and what it meant to be a human. And at the same time, it was a beautifully done "coming of age" story of sorts.
(and now those who watched that series can now cry as they see the below pic)
My first would be Rukia! segundo is Golden Darkness a.k.a Yami-chan. She's not from a very known animê To amor Ru. WHY? Because she's adorable!! We both don't like Echhi people! Plus she's strong alien girl, who can turn her hair in to any weapon! She always has these Japanese snacks that are shaped like peixe (forgot the name). Plus her usual expression reminds me of Yuki Nagato's expression!